A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP
نویسندگان
چکیده
منابع مشابه
Automated ARGET ATRP Accelerates Catalyst Optimization for the Synthesis of Thiol-Functionalized Polymers.
Conventional synthesis of polymers by ATRP is relatively low throughput, involving iterative optimization of conditions in an inert atmosphere. Automated, high-throughput controlled radical polymerization was developed to accelerate catalyst optimization and production of disulfide-functionalized polymers without the need of an inert gas. Using ARGET ATRP, polymerization conditions were rapidly...
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متن کاملسنتز نانوکامپوزیتهای پلیاستیرن/MCM–41 به روشهای AGET ATRP و ARGET ATRP
نانوکامپوزیتهای پلیاستیرن/MCM–41 به روش پلیمرشدن رادیکالی انتقال اتم (ATRP) در دمای 110 درجه سلسیوس سنتز شدند. روشهای آغاز فعالکنندههایی که با انتقال الکترون تولید میشوند (AGET) و فعالکنندههایی که با انتقال الکترون بازتولید میشوند (ARGET) به عنوان دو روش نوین آغاز در ATRP به کار گرفته شدند. ساختار ویژه، مساحت سطح، اندازه ذرات و توزیع آنها و ساختار اسفنجی و حفرهای نانوذرات MCM–41 سنت...
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ژورنال
عنوان ژورنال: Polymer Chemistry
سال: 2016
ISSN: 1759-9954,1759-9962
DOI: 10.1039/c6py01844k